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MPD
CAS No. 4457-71-0MPD (3-Methyl-1,5-pentanediol) is a diol which is an isomer of 1,6-hexanediol. MPD is amorphous, giving excellent properties to polyurethanes.: outstanding softness, high transparency and compatibility, owing to the methyl branch in the middle of its structure.
ND
CAS No. 3937-56-2ND (1,9-Nonanediol) is a diol with a straight chain alkyl group. The melting point is relatively high thanks to the log chain, but a viscosity of 60oC is the same as acetone.
Features
■ MPD
Softness
Kuraray Polyol inhibits cohesion. This allows for increased operating efficiency.
Hydrolysis resistance
Hydrolysis resistance is good; MPD can inhibit the hydrolysis resistance of polyurethanes.
■ ND
Appropriate crystallinity
By moderately disrupting orientation (crystallinity), it imparts strength and flexibility to polyurethane.
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Left:MPD at room temp.
Right:ND heating at 60oC
Hydrolysis resistance (MPD)
The hydrolysis resistance of PU resin from MPD-based polyester polyol is high even MPD portion is small as an ingredient of polyester polyol.
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Appropriate crystallinity (ND)
Compared to diols with even carbon numbers, molecular chains are less likely to be oriented, and crystallinity is appropriately suppressed, resulting in a lower melting point. The moderate crystallinity gives the resin strength and flexibility and improves transparency.
Applications
MPD
- Polyurethanes (polyols, chain extenders)
- Solvents
- Acrylate Monomer
ND
- Polyurethanes (polyols, chain extenders)
- Polyester
- UV monomer, oligomer
- Acrylate Monomer